TY  - JOUR
A1  - Loew, Noya
A1  - Bogdanoff, Peter
A1  - Herrmann, Iris
A1  - Wollenberger, Ursula
A1  - Scheller, Frieder W.
A1  - Katterle, Martin
T1  - Influence of modifications on the efficiency of pyrolysed CoTMPP as electrode material for horseradish peroxidase and the reduction of hydrogen peroxide
T2  - Electroanalysis : an international journal devoted to fundamental and practical aspects of electroanalysis
N2  - A tailor-made horseradish peroxidase (HRP) bulk composite electrode was developed on the basis of pyrolyzed cobalt tetramethoxyphenylporphyrin (CoTMPP) by modifying pore size and surface area of the porous carbon material through varying amounts of iron oxalate and sulfur prior to pyrolyzation. The materials were used to immobilize horseradish peroxidase (HRP). These electrodes were characterized in terms of their efficiency to reduce hydrogen peroxide. The heterogeneous electron transfer rate constants of different materials were determined with the rotating disk electrode method and a k(S) (401 +/- 61 s(-1)) exceeding previously reported values for native HRP was found.
KW  - cobalt porphyrin
KW  - electron transfer
KW  - horseradish peroxidase
KW  - hydrogen peroxide
KW  - immobilization
Y1  - 2006
UR  - https://publishup.uni-potsdam.de/frontdoor/index/index/docId/46055
SN  - 1040-0397
VL  - 18
IS  - 23
SP  - 2324
EP  - 2330
PB  - Wiley-VCH
CY  - Weinheim
ER  -