TY  - GEN
A1  - König, Jana
A1  - Kelling, Alexandra
A1  - Schilde, Uwe
A1  - Strauch, Peter
T1  - [µ2-O,O′,Oʺ,Oʺ′-Bis(1,2-dithiooxalato-S,S′)nickel(II)]bis[-O,O′-bis(1,2-dithiooxalato-S,S′)-nickel(II)pentaquaholmium(III)]hydrate, [Ho2Ni3(dto)6(H2O)10]
N2  - Planar bis(1,2-dithiooxalato)nickelate(II), [Ni(dto)]2− reacts in aqueous solutions with lanthanide ions (Ln3+) to form pentanuclear, hetero-bimetallic complexes of the general composition [{Ln(H2O)n}2{Ni(dto)2}3]·xH2O. (n = 4 or 5; x = 9–12). The complex [{Ho(H2O)5}2{Ni(dto)2}3]·10H2O, Ho2Ni3, was synthesized and characterized by single crystal X-ray structure analysis and powder diffraction. The Ho2Ni3 complex crystallizes as monoclinic crystals in the space group P21/c. The channels and cavities, appearing in the crystal packing of the complex molecules, are occupied by a varying amount of non-coordinated water molecules.
T3  - Zweitveröffentlichungen der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe - 360 
KW  - lanthanides
KW  - holmium(III)
KW  - 1,2-dithiooxalate
KW  - crystal structure
KW  - nickel(II)
Y1  - 2017
UR  - https://publishup.uni-potsdam.de/frontdoor/index/index/docId/40059
UR  - https://nbn-resolving.org/urn:nbn:de:kobv:517-opus4-400598
ER  -