TY  - JOUR
A1  - Kreye, Oliver
A1  - Toth, Tommy
A1  - Meier, Michael A. R.
T1  - Introducing multicomponent reactions to polymer science passerini reactions of renewable monomers
T2  - Journal of the American Chemical Society
N2  - Combination of the Passerini three component-reaction (3CR) and olefin metathesis led to the formation of poly[1-(alkyl carbamoyl)alkyl alkanoates], a new class of polyesters with amide moieties in their side chain, from renewable resources. Two different approaches were studied and compared to each other. First, monomers were synthesized by the Passerini-3CR and then polymerized via acyclic diene metathesis. Alternatively, bifunctional monomers were synthesized by self-metathesis and then polymerized by Passerini-3CR. Both approaches led to the formation of high-molecular-weight polymers. Moreover, Passerini-3CRs were shown to be a versatile grafting-onto method. The results clearly demonstrate that the Passerini-3CR offers an interesting new access to monomers and polymers and thus broadens the synthetic portfolio of polymer science.
Y1  - 2011
UR  - https://publishup.uni-potsdam.de/frontdoor/index/index/docId/37016
SN  - 0002-7863
VL  - 133
IS  - 6
SP  - 1790
EP  - 1792
PB  - American Chemical Society
CY  - Washington
ER  -