TY - JOUR A1 - Lange, Ilja A1 - Reiter, Sina A1 - Kniepert, Juliane A1 - Piersimoni, Fortunato A1 - Paetzel, Michael A1 - Hildebrandt, Jana A1 - Brenner, Thomas J. K. A1 - Hecht, Stefan A1 - Neher, Dieter T1 - Zinc oxide modified with benzylphosphonic acids as transparent electrodes in regular and inverted organic solar cell structures T2 - Applied physics letters N2 - An approach is presented to modify the work function of solution-processed sol-gel derived zinc oxide (ZnO) over an exceptionally wide range of more than 2.3 eV. This approach relies on the formation of dense and homogeneous self-assembled monolayers based on phosphonic acids with different dipole moments. This allows us to apply ZnO as charge selective bottom electrodes in either regular or inverted solar cell structures, using poly(3-hexylthiophene): phenyl-C71-butyric acid methyl ester as the active layer. These devices compete with or even surpass the performance of the reference on indium tin oxide/poly(3,4-ethylenedioxythiophene) polystyrene sulfonate. Our findings highlight the potential of properly modified ZnO as electron or hole extracting electrodes in hybrid optoelectronic devices. (C) 2015 AIP Publishing LLC. Y1 - 2015 UR - https://publishup.uni-potsdam.de/frontdoor/index/index/docId/39083 SN - 0003-6951 SN - 1077-3118 VL - 106 IS - 11 PB - American Institute of Physics CY - Melville ER -