From molecular precursors to nanoparticles
- Nanoporous carbon materials (NCMs) provide the "function" of high specific surface area and thus have large interface area for interactions with surrounding species, which is of particular importance in applications related to adsorption processes. The strength and mechanism of adsorption depend on the pore architecture of the NCMs. In addition, chemical functionalization can be used to induce changes of electron density and/or electron density distribution in the pore walls, thus further modifying the interactions between carbons and guest species. Typical approaches for functionalization of nanoporous materials with regular atomic construction like porous silica, metal-organic frameworks, or zeolites, cannot be applied to NCMs due to their less defined local atomic construction and abundant defects. Therefore, synthetic strategies that offer a higher degree of control over the process of functionalization are needed. Synthetic approaches for covalent functionalization of NCMs, that is, for the incorporation of heteroatoms into theNanoporous carbon materials (NCMs) provide the "function" of high specific surface area and thus have large interface area for interactions with surrounding species, which is of particular importance in applications related to adsorption processes. The strength and mechanism of adsorption depend on the pore architecture of the NCMs. In addition, chemical functionalization can be used to induce changes of electron density and/or electron density distribution in the pore walls, thus further modifying the interactions between carbons and guest species. Typical approaches for functionalization of nanoporous materials with regular atomic construction like porous silica, metal-organic frameworks, or zeolites, cannot be applied to NCMs due to their less defined local atomic construction and abundant defects. Therefore, synthetic strategies that offer a higher degree of control over the process of functionalization are needed. Synthetic approaches for covalent functionalization of NCMs, that is, for the incorporation of heteroatoms into the carbon backbone, are critically reviewed with a special focus on strategies following the concept "from molecules to materials." Approaches for coordinative functionalization with metallic species, and the functionalization by nanocomposite formation between pristine carbon materials and heteroatom-containing carbons, are introduced as well. Particular focus is given to the influences of these functionalizations in adsorption-related applications.…
Author details: | Milena PerovicORCiDGND, Qing QinORCiDGND, Martin OschatzORCiDGND |
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DOI: | https://doi.org/10.1002/adfm.201908371 |
ISSN: | 1616-301X |
ISSN: | 1616-3028 |
Title of parent work (English): | Advanced functional materials |
Subtitle (English): | tailoring the adsorption properties of porous carbon materials by controlled chemical functionalization |
Publisher: | Wiley-VCH |
Place of publishing: | Weinheim |
Publication type: | Article |
Language: | English |
Date of first publication: | 2020/01/09 |
Publication year: | 2020 |
Release date: | 2023/03/23 |
Tag: | composites; functionalization; heteroatoms; metal species; porous carbon materials; surface |
Volume: | 30 |
Issue: | 41 |
Article number: | 1908371 |
Number of pages: | 21 |
Funding institution: | Deutsche Forschungsgemeinschaft (DFG, German Research Foundation) under; Germany's Excellence StrategyGerman Research Foundation (DFG) [EXC; 2008/1, 390540038]; Liebig Stipendium from the German Chemical Industry; Fund; German-Israeli Foundation for Scientific Research and Development; (GIF)German-Israeli Foundation for Scientific Research and Development; [I-87-302.10-2015] |
Organizational units: | Mathematisch-Naturwissenschaftliche Fakultät / Institut für Chemie |
DDC classification: | 5 Naturwissenschaften und Mathematik / 53 Physik / 530 Physik |
5 Naturwissenschaften und Mathematik / 54 Chemie / 540 Chemie und zugeordnete Wissenschaften | |
6 Technik, Medizin, angewandte Wissenschaften / 62 Ingenieurwissenschaften / 620 Ingenieurwissenschaften und zugeordnete Tätigkeiten | |
Peer review: | Referiert |
Publishing method: | Open Access / Hybrid Open-Access |
License (German): | CC-BY-NC - Namensnennung, nicht kommerziell 4.0 International |
External remark: | Zweitveröffentlichung in der Schriftenreihe Postprints der Universität Potsdam : Mathematisch-Naturwissenschaftliche Reihe ; 1191 |